By F.G.A. Stone, Robert West

ISBN-10: 0120311151

ISBN-13: 9780120311156

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Mingos, D. M. , J . Chem. SOC. Dalton Trans. 31 (1977). 159. Mingos, D. M. ,J. Chem. Dalton Trans. 1163 (1976). 160. Mingos, D. M. , Heathcock, S. , and Tuney, T. , J . Chem. Soc. Dalton Trans. 204 (1977). 161. Moore, J. , Acta Chem. Scand. 20, 1154 (1966). 162. Muir, L. , Muir, K. , and Ibers, J. , Discuss. Faraday SOC. 47, 84 (1969). 163. Mulliken, R. , J . Chem. Phys. 23, 1833 (1955). 164. Murrell, J. , and Harget, A. ” Wiley (Interscience), New York, 1972. 165. Murrell, J. , and Vincent, I.

22 D. M. P. MINGOS L iqand ontisymmetric combination FIG. 9. Interaction diagram for the antisymmetric orbitals of the angular ML, fragment. , the antisymmetric combination of ligand orbitals. If the interaction overlaps are chosen to be positive as they are shown in the Fig. 9, then the numerator in expression (8) is positive. The sign of expression (8) is determined by the energy denominator. From the level ordering EL < E,, < Ex, the sign of expression (8) is negative for the donor orbital of the ML, fragment and, therefore, p , (with the phase defined in Fig.

And Johnson, K. , Phys. Rev. B 5 , 844 (1972). 209. Smith, W. ” Dekker, New York, 1974. 210. , MTP Int. Rev. , Znorg. Chem. Ser. ZZ, 1, 200 (1975). 211. Sohn, Y. , Hendnckson, D. , Smith, J . , and Gray, H. , Chem. Phys. Lett. 6, 499 (1970). 212. Sohn, Y. , Hendrickson, D. , and Gray, H. , J . Amer. Chem. SOC. 93, 3603 (1971). 213. Stevenson, D. , Wei, C. , and Dahl, L. , J . Amer. Chem. SOC. 93, 6027 ( I97 1). 214. Stone, F. G. A . , J . Organometal. Chem. 100, 257 (1975). 215. Stone, F. G. , Pure A p p f .

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Advances in Organometallic Chemistry, Vol. 15 by F.G.A. Stone, Robert West

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