By Robert C. West, Anthony F. Hill, Mark J. Fink

ISBN-10: 0123739780

ISBN-13: 9780123739780

Just about all branches of chemistry and fabric technology now interface with organometallic chemistry - the examine of compounds containing carbon-metal bonds. This generally acclaimed serial includes authoritative experiences that deal with all facets of organometallic chemistry, a box which has improved tremendously because the book of quantity 1 in 1964.* presents an authoritative, definitive overview addressing all facets of organometallic chemistry* helpful to researchers inside this energetic box and is a needs to for each smooth library of chemistry* top of the range study booklet inside of this swiftly constructing box

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Extra info for Advances in Organometallic Chemistry, Vol. 55

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170 Silicone polyethers (SPE) 51, also known as silicone-copolyols (SCP), which are readily prepared via hydrosilation [Eq. (31)], form a very important class of copolymers in the area of commercial surfactants. Their utility, however, goes beyond the surface properties as they are also highly suited for ion conduction in polymeric liquid, gel or solid battery applications. 175 Polysiloxanes with pendent cyclic carbonate176 and sulfonate groups177 were also reported earlier for this application.

28)]. 5 equiv Ph2SiH2, 2 mol% 38, R1 THF, 15 °C, 24 h. 2 mol% AgBF4, R1 CH2Cl2, - 60 °C, 10 h. K. ROY highly effective for the enantioselective hydrosilation of phenyl/alkyl or dialkyl ketones with Ar2SiH2 (ArQPh or 3-F-C6H4). 144 Korostylev et al. 146 Good to high yields and high to often exceptional (95 to 499%) enantioselectivity were achieved, at room temperature in CH2Cl2. Again, the Re(V) complex stands out as a high oxidation state metal catalyst that is insensitive to air and moisture exposure.

106 Functionalities on the ketone substrate such as halide, ether and tertiary amine are well tolerated and excellent conversions are achievable using a number of variations of 25 (pre-synthesized or generated in situ) with different N-substitution on the ring. Cl Cu N N 25 R1R2C=O + R3SiH 3 mol% (NHC) CuCl Toluene, 80°C NHC = N-Heterocyclic Carbene R1R2CH OSiR3 (19) 65-99% VII CATALYSIS BY ACIDS, BASES, OR FREE RADICALS The use of Lewis acids as catalysts for the hydrosilation of unsaturated compounds, hydrocarbons in particular, has seen a surge of interest and activity over the last dozen years.

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Advances in Organometallic Chemistry, Vol. 55 by Robert C. West, Anthony F. Hill, Mark J. Fink

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