By Peter A. Thrower, Ljubisa R. Radovic

ISBN-10: 082479091X

ISBN-13: 9780824790912

This twenty fourth quantity keeps within the culture of its predecessors, providing authoritative, interdisciplinary insurance of up to date themes within the box of carbon chemistry and physics. With contributions by means of prime overseas specialists, this quantity: describes pitch polymerization kinetics in the course of mesophase formation and the structure of coexisting stages in mesophase pitch in the course of warmth remedy; elucidates the mechanism of mesophase formation and pitch polymerization kinetics after mesophase formation; examines the significance of actual, solid-state, electro- and analytical chemistry within the examine of carbon surfaces; discusses the theoretical historical past for the thermal conductivity of diamonds, unmarried crystal diamonds and chemically-vapour-deposited diamond movies; and explains the chemistry inquisitive about the economic fabrication and use of needle coke.

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Additional resources for Chemistry and Physics of Carbon, Vol. 26

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27) show that, inpitch, 100% anisotropy occurs well before solidification 109-1 101. Figure 27 shows A240 carbonizedin standard conditions (heating rate 4°C rnin-l, full circles) and A240 carbonized at 0S"C min-l (open circles). At 4°C rnin-l, LMO occurs at 465°C (110 single mow), 100%anisotropy occursat 5SO"C (230 MPa, double mow), solidification is over at 600°C (asyrnptot). 5" C rnin-l, LMO occurs at 420-430°C (180 MPa, (120 MPa, single arrow), 100% anisotropy occurs at 490°C HTT double arrow), solidification is over at 550°C.

15). In a perfect azimuthal orientation of all BSU in a plane,the common 002 reflection lies along the normal to the aromatic layers. If the preferred orientation plane is chosen as ZOX, 002 lies alongY* (case 1). If there is no orientation atall (case 2), the locusof the 002 reciprocal nodes is a sphere centered on the incident beam (powder sphere) around which the002 nodes are uniformly distributed. In the case of an LMO, a small amount of ~sorientationoccurs relative to the preferred orientation plane ZOX (case 3) either by twist around OZ or tilt around OX.

18 and Section IV A 3). However, it may be noted that BSU-like stacks have been observed in asphaltenes and not so clearly in weakly evolved kerogensof Series I and 11. This may be explained in two ways, (1) they may be present but their concentration is which do not exclude each other: toolowtobedetectedbythetechniquesused(TEM),whiletheyaremore concentrated in asphaltenes and(2) the association of polyaromatic molecules in stacksmaybeabsent, due tolack of mobility,but it mayoccurwhenthe polyaromatic molecules are brought into a fluid phase.

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Chemistry and Physics of Carbon, Vol. 26 by Peter A. Thrower, Ljubisa R. Radovic


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