By J. A. McCleverty, T. J. Meyer

ISBN-10: 0080437486

ISBN-13: 9780080437484

ISBN-10: 0080443311

ISBN-13: 9780080443317

Complete Coordination Chemistry II (CCC II) is the sequel to what has turn into a vintage within the box, entire Coordination Chemistry, released in 1987. CCC II builds at the first and surveys new advancements authoritatively in over two hundred newly comissioned chapters, with an emphasis on present developments in biology, fabrics technology and different components of latest medical curiosity.

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Extra resources for Comprehensive Coordination Chemistry II: From Biology to Nanotechnology (10 Volumes Set)

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53% after 320 h in the absence of (251)). The rate enhancement is due to activation of the lactone towards nucleophilic attack by binding to the Lewis acidic center of (251). 776 In the latter case the propagating species is an aluminum enolate and this too may initiate the ROP of lactones, such as -VL, albeit slowly. 787 A range of tetradentate Schiff-base ligands have also been employed to prepare discrete aluminum alkoxides. The most widely studied system is the unsubstituted parent system (256), which initiates the controlled ROP of rac-LA at 70  C in toluene.

554 33 Metal Complexes as Catalysts for Polymerization Reactions Well-defined nanoclusters (%10–100 A˚ diameter) of several metals have been prepared via the polymerization of metal-containing monomers. The synthetic approach involves the block copolymerization of a metallated norbornene with a hydrocarbon co-monomer which is used to form an inert matrix. Subsequent decomposition of the confined metal complex affords small clusters of metal atoms. 613,614 Me (223) (224) (225) Pt Me Pd Ph (226) Pb(CF3SO3) Me Me Alternatively a non-metallated chelating monomer such as (227) or (228) may be copolymerized with (223) and the metal introduced post-polymerization.

683 Several reports of Ru initiators with chelating diphosphine ligands have appeared;684–687 it is currently unclear how relevant the phosphine dissociation mechanism described above is to such complexes. 690–692 A wide range of functionalities are tolerated, including ethers, esters, amines, amides, alcohols, carboxylic acids, and ketones. 693 Degradation of the acetal junctions affords hydroxyl end groups. (244) may also be polymerized by (232), (233), (237), or (238) in the presence of allylic difunctionalized chain transfer agents.

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Comprehensive Coordination Chemistry II: From Biology to Nanotechnology (10 Volumes Set) by J. A. McCleverty, T. J. Meyer


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